Palladium-catalyzed preparation of exo-aryl derivatives of the norbornane skeleton

…, F Marinelli, E Bernocchi, S Cacchi, G Ortar

文献索引：Arcadi, A.; Marinelli, F.; Bernocchi, E.; Cacchi, S.; Ortar, G. Journal of Organometallic Chemistry, 1989 , vol. 368, p. 249 - 256

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被引用次数: 63

摘要

Abstract Norbornene and norbornadiene derivatives have been shown to react with aryl and vinyl halides in the presence of a palladium catalyst, formic acid, and tributylamine or piperidine to give hydroarylated and hydrovinylated derivatives in good to high yield. Extension of the reaction to the hindered α, β-unsaturated aldehydic system of myrtenal produced a monocyclic derivative through a palladium-catalyzed ring opening.