The Journal of Organic Chemistry

Ionic reactions in the spiran series. III. Solvolysis of medium-sized-ring spiro compounds

AP Krapcho, JE McCullough

文献索引：Krapcho,A.P.; McCullough,J.E. Journal of Organic Chemistry, 1967 , vol. 32, p. 2453 - 2458

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被引用次数: 3

摘要

The first-order rate constants, the products, and the activation parameters for the acetolysis of 2, a-dimethylcyclooctyl p-nephthalenesulfonate and several medium-sized-ring spiran esters have been determined. The spiro compounds studied were 1 with m= 8 and n= 5, 6, and 7; 1 with m= 6 and n= 7; and 1 with m= 9 and n= 8. The 2, 2-dimethylcyclooctylp- naphthalenesulfonate yielded products arising exclusively from ring contraction. For the ...