Nickela-heteroringe aus nickel (0) und phenylisocyanat

H Hoberg, BW Oster, C Krüger, YH Tsay

文献索引：Hoberg, H.; Oster, B.W.; Krueger, C.; Tsay, Y.H. Journal of Organometallic Chemistry, 1983 , vol. 252, # 3 p. 365 - 373

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被引用次数: 31

摘要

Abstract Phenylisocyanate reacts with (Lig) Ni 0 systems in various ways depending on the ligand (Lig). Thus, with TMEDA as ligand, headtail linkage of the isocyanates occurs to give the nickela-5-ring (II), whereas triethylphosphine ligand causes the formation of a nickela-6- ring (V). The structure of II was determined chemically and that of V by X-ray analysis. The properties of these novel cyclic nickela compounds are described and the reaction ...