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The Journal of Organic Chemistry

Silicon Heterocyclic Compounds. II. Synthesis of 3-Sila-1-heterocycloheptanes1

RJ Fessenden, MD Coon

文献索引:Fessenden,R.J.; Coon,M.D. Journal of Organic Chemistry, 1964 , vol. 29, p. 2499 - 2501

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被引用次数: 14

摘要

The reports of silaheterocycloheptanes are sparse3; the parent silacycloheptane and a few of its derivatives have been reported and st~ died.~ The key step in the synthesis of the silaheterocyclohexanes was a silicon hydride addition to a silyl-blocked allyl alcohol. This study differs in that the key intermediate, 6-hydroxybutyl (chloroniethyl) dimethylsilane