Oxidation of aminophenols by 4a-hydroperoxy-5-ethyllumiflavin anion. Flavoenzyme hydroxylase mechanism

SR Keum, DH Gregory, TC Bruice

文献索引：Keum; Gregory; Bruice Journal of the American Chemical Society, 1990 , vol. 112, # 7 p. 2711 - 2715

被引用次数: 16

摘要

Abstract: Product and kinetic studies have been carried out (absolute f-BuOH solvent, 0,-free Nz atmosphere, 30" C) for the oxidation of a number of aminophenolate anions (0-, m-, and p-amino, 2-amino-5-methy1, 3-methyl-4-amin0, pN, N-dimethylamino) and aminonaphtholate anions (1-amino-2-naphtholate, 4-amino-1-naphtholate, 2-amino-3- naphtholate) by the hydroperoxy anion of 5-ethyl-3-methyl-4a, 5-dihydro-4a- ...

~78%

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