The Journal of Organic Chemistry

Ring enlargements. XI. Structural influences on the course of the intramolecular diazo alkane-carbonyl reaction

CD Gutsche, JE Bowers

文献索引：Gutsche,C.D.; Bowers,J.E. Journal of Organic Chemistry, 1967 , vol. 32, p. 1203 - 1212

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被引用次数: 7

摘要

spectrum which shows absorptions at 1710 and 1130 cm-', characteristic of a cyclohexanone carbonyl group and an ether group, respectively5 (Scheme 111). The possibility that the purified sample of 9 might be contaminated with fused ring isomer 11 was excluded on the basis of the following experiment. Admixture of the reaction product with 2, 2, 6, 6-tetramethylcyclohexanone (a nonenolizable and hence difficultly oxidizable ketone ...