Formation of dialkyl. ALPHA.-siloxybenzylphosphonate via 1, 2-anionic rearrangement of a silyl group.

A Sekiguchi, M Ikeno, W Ando

文献索引：Sekiguchi,A. et al. Bulletin of the Chemical Society of Japan, 1978 , vol. 51, p. 337 - 338

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被引用次数: 14

摘要

The reactions of silyl phenyl ketones with trialkyl phosphites and dialkyl sodiophosphonates gave dialkyl α-siloxybenzylphosphonates in good yields. The mechanism involves the migration of a silyl group from carbon to anionic oxygen. No deoxygenation of silyl ketone with trialkyl phosphite was observed.