Journal of the American Chemical Society

Reactions of Some Aromatic Acetylenic Carbinols1

GF Hennion, BR Fleck

文献索引：Hennion; Fleck Journal of the American Chemical Society, 1955 , vol. 77, p. 3253,3257

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被引用次数: 30

摘要

9-Ethynyl-9-fluoreno1, diphenylethynylcarbinol and phenylmethylethynylcarbinol have been hydrated to the expected methyl ketones. Some hydroxyl group reactions of the ethynylcarbinols and of the a-ketols obtained by hydration have been studied also. In none of these reactions has rearrangement of the carbon skeleton been observed. The ethynylcarbinols underwent the Meyer-Schuster rearrangement and thus produced ...