Reactions of synthetic [2Fe-2S] and [4Fe-4S] clusters with nitric oxide and nitrosothiols
…, ZJ Tonzetich, E Reisner, SJ Lippard
文献索引：Harrop, Todd C.; Tonzetich, Zachary J.; Reisner, Erwin; Lippard, Stephen J. Journal of the American Chemical Society, 2008 , vol. 130, # 46 p. 15602 - 15610
The interaction of nitric oxide (NO) with iron− sulfur cluster proteins results in degradation and breakdown of the cluster to generate dinitrosyl iron complexes (DNICs). In some cases the formation of DNICs from such cluster systems can lead to activation of a regulatory pathway or the loss of enzyme activity. In order to understand the basic chemistry underlying these processes, we have investigated the reactions of NO with synthetic [2Fe-2S] and [ ...
