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The Journal of Organic Chemistry

Silicon hydrides and molybdenum (0) catalyst: a novel approach for conjugate reduction of. alpha.,. beta.-unsaturated carbonyl compounds

E Keinan, D Perez

文献索引:Keinan, Ehud; Perez, Daniel Journal of Organic Chemistry, 1987 , vol. 52, # 12 p. 2576 - 2580

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被引用次数: 69

摘要

A novel reducing system comprised of phenylsilane and catalytic amounts of MO (CO)~ in refluxing THF efficiently effects conjugate reduction of Michael acceptors, including a, &unsaturated ketones, carboxylic acids, carboxylic esters, amides, and nitriles. The ...