Tetrahedron

The mild oxidation of nitrile oxides affords a convenient entry to nitrosocarbonyl intermediates, versatile tools in organic syntheses

P Quadrelli, M Mella, AG Invernizzi, P Caramella

文献索引：Quadrelli; Mella; Gamba Invernizzi; Caramella Tetrahedron, 1999 , vol. 55, # 34 p. 10497 - 10510

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被引用次数: 41

摘要

Nitrile oxides are oxidized by tertiary amine N-oxides in different solvents at room temperature to afford in the presence of dienes nitrosocarbonyl adducts in fair yields. The mild conditions used in oxidizing a variety of nitrile oxides promise a wide application of this method in synthetic processes.