Carbohydrate research

The heterogeneous, catalytic, transfer hydrogenolysis of tri-O-benzyl derivatives of 1, 6-anhydro-β-D-hexopyranoses

MC Cruzado, M Martin-Lomas

文献索引：Cruzado, M. Carmen; Martin-Lomas, Manuel Carbohydrate Research, 1987 , vol. 170, p. 249 - 254

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被引用次数: 4

摘要

Heterogeneous, catalytic, transfer hydrogenolysisl may result in enhanced selectivity in the deprotection of benzyl ethers of polyols and has been utilised in carbohydrate chemistry2~ 3. Our preliminary results4 indicated that, in conformationally rigid molecules, benzyl groups may act as hydrogen donors and partially O-benzoylated derivatives could be obtained when the reaction was carried out in the presence 'of atmospheric oxygen. We now report ...