The direct electrochemical synthesis of dialkyldithiocarbamate and diethyldithiophosphate complexes of main group and transition metals

C Geloso, R Kumar, JR Lopez-Grado…

文献索引：Geloso, Corrado; Kumar, Rajesh; Lopez-Grado, Jaime Romero; Tuck, Dennis G. Canadian Journal of Chemistry, 1987 , vol. 65, p. 928 - 932

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被引用次数: 18

摘要

Dialkyldithiocarbamate derivatives (R2NCS2) n M of a number of metals (M= Fe, Co, Ni, Cu, Ag, Zn, Cd, In, Tl) have been synthesised in good yield by electrochemical oxidation of appropriate sacrificial anodes in non-aqueous solutions of either the corresponding tetraalkylthiuram disulphide (R2NCS2) 2 (R= Me, Et) or a mixture of carbon disulphide plus the secondary amine R2NH (R= Et, i-Pr; R2NH= piperidine). Similar experiments with ...