Reactions of α-Haloalkaneboronic Esters1a

DS Matteson, GD Schaumberg

文献索引：Matteson,D.S.; Schaumberg,G.D. Journal of Organic Chemistry, 1966 , vol. 31, p. 726 - 731

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被引用次数: 38

摘要

Results Haloalkaneboronic Esters.-In previous work, 6 dibutyl vinylboronate (1) was found to be inert to liquid hydrogen bromide at-70". We have now found that in refluxing hydrogen iodide a mixture of dibutyl 1-iodoethaneboronate (2) and 2-iodoethaneboronate (3) is formed in about 60% yield. The proportion of 1 isomer 2 was found to be 62% by nmr, based on the