Free energy and solvent dependence of intramolecular electron transfer in donor-substituted rhenium (I) complexes

DB MacQueen, KS Schanze

文献索引：Brent MacQueen; Schanze, Kirk S. Journal of the American Chemical Society, 1991 , vol. 113, # 20 p. 7470 - 7479

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被引用次数: 102

摘要

Abstract: A comprehensive investigation of photoinduced intramolecular electron transfer (ET) in a series of six complexes of the typefac-(b) Rei (CO) 3-D (where b is a diimine ligand and D is a dimethylaniline electron donor) is reported. Photoexcitation of the dx (Re)- x*(diimine) metal-teligand chargetransfer excited state initiates a sequence of forward and back ET reactions:(b) Rei (CO) 3-D-he (b-) Reii (CO) 3-D-km (b-) Re'(CO),-D+ kser (b) Rei ...