Journal of the American Chemical Society

Alkylation of carbon-metallic compounds with trialkyl phosphates

H Gilman, BJ Gaj

文献索引：Gilman,H.; Gaj,B.J. Journal of the American Chemical Society, 1960 , vol. 82, p. 6326 - 6329

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被引用次数: 19

摘要

Recently we reported the reactions of trialky1112 and triary13 phosphate esters with triphenylsilyllithium in tetrahydrofuran. The alkyl esters were found to react in a 1: 1 mole ratio with this silylmetallic compound via nucleophilic displacements of oxygen from carbon, giving alkyltriphenylsilanes in high yields. 3 The use of three equivalents of triphenylsilyllithium and forced conditions in reactions with tri-n-butyl phosphate, however, ...