The Journal of Organic Chemistry

Synthesis of 1-trimethylsilyl 1, 3-dienes by the palladium-catalyzed reaction of trimethylvinylsilane with vinyl iodides/silver nitrate or vinyl triflates

K Karabelas, A Hallberg

文献索引：Karabelas, Kostas; Hallberg, Anders Journal of Organic Chemistry, 1988 , vol. 53, # 21 p. 4909 - 4914

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被引用次数: 75

摘要

Multifunctionalized 1-trimethylsilyl 1, 3-dienes often exhibit high reactivity and regio-and stereospecificity toward dienophiles' and electrophiles. 2 Consequently, these dienes are becoming well established as useful intermediates in organic synthesis, suggesting that efficient synthetic methods3 for their preparation are desirable. Palladium-catalyzed vinylation of olefins, the Heck reaction," should in principle serve as an attractive ...