Interplay of Self-Association and Solvation in Polar Liquids
V Amenta, JL Cook, CA Hunter, CMR Low…
文献索引：Amenta, Valeria; Cook, Joanne L.; Hunter, Christopher A.; Low, Caroline M. R.; Sun, Hongmei; Vinter, Jeremy G. Journal of the American Chemical Society, 2013 , vol. 135, # 32 p. 12091 - 12100
The association constants for formation a 1: 1 complex between 4-phenyl azophenol and tri- n-butylphosphine oxide were measured in mixtures of n-octane and n-decanol, n-octane and n-hexanoic acid, and n-octane and 2-ethylhexyl acetamide. The experiments provide insight into the competition between solvent self-association and solvent–solute interactions in these systems. The solvation properties of the three polar solvents are quite different ...
