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Journal of Organic Chemistry 2007-06-08

New chiral binaphthalene-derived iminium salt organocatalysts for asymmetric epoxidation of alkenes.

Philip C Bulman Page, Mohamed M Farah, Benjamin R Buckley, A John Blacker

文献索引:J. Org. Chem. 72 , 4424, (2007)

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摘要

A series of binaphthalene-fused azepinium salts has been generated and used as organocatalysts in the asymmetric epoxidation of unfunctionalized alkenes, giving rise to ees of up to 84%.

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