Synthesis of dioxazaborocines from N-substituted-bis (2-hydroxyaryl) aminomethylamines

PD Woodgate, GM Horner, NP Maynard…

文献索引：Woodgate, Paul D.; Horner, Gillian M.; Maynard, N. Paul; Rickard, Clifton E.F. Journal of Organometallic Chemistry, 1999 , vol. 592, # 2 p. 180 - 193

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被引用次数: 11

摘要

The preparation of a number of tripodal amines from aminoalkylation of 1, 3-benzoxazines by phenols is presented. A series of ligands prepared in this manner were successfully coordinated to boron, giving dioxazaborocines. X-ray crystal structures of two analogues are reported. These compounds are capable of releasing borate ions and are therefore potentially biologically active.