Kinetics of reductive NO bond fragmentation: the role of a conical intersection

ED Lorance, WH Kramer, IR Gould

文献索引：Lorance, Edward D.; Kramer, Wolfgang H.; Gould, Ian R. Journal of the American Chemical Society, 2002 , vol. 124, # 51 p. 15225 - 15238

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被引用次数: 56

摘要

N-alkoxyheterocycles can act as powerful one-electron acceptors in photochemical electron- transfer reactions. One-electron reduction of these species results in formation of a radical that undergoes NO bond fragmentation to form an alkoxy radical and a neutral heterocycle. The kinetics of this NO bond fragmentation reaction have been determined for a series of radicals with varying substituents and extents of delocalization. Rate constants varying ...