Synthesis

Acyloxylation of 1-methoxycyclohex-1-ene and other enol ethers with dimethyl peroxydicarbonate

K Schank, H Beck, S Pistorius, T Rapold

文献索引：Schank; Beck; Pistorius; Rapold Synthesis, 1995 , # 8 p. 964 - 968

全文：HTML全文

被引用次数: 3

摘要

Acyloxylation of different types of enol ethers (derived from aldehydes and ketones) by dimethyl peroxydicarbonate (DPDC) results in either addition to the double bond or in a formal replacement of an allylic hydrogen by a methoxycarbonyloxy group forming vicinal oxygenated hydrocarbons. 1, 3-Oxygenated products via monoacyloxylation could not be observed. The results are compared with copper (I)-catalyzed acyloxylations of 1- ...