Tetrahedron letters

New synthetic route to diaminonitropyrazoles as precursors of energetic materials

J Guillard, F Goujon, P Badol, D Poullain

文献索引：Guillard, Jerome; Goujon, Fanny; Badol, Perrine; Poullain, Didier Tetrahedron Letters, 2003 , vol. 44, # 31 p. 5943 - 5945

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被引用次数: 6

摘要

Treatment of nitropyrimidine derivatives with (N-substituted) hydrazines (2 equiv.) gave 1- (substituted)-3, 5-diamino-4-nitropyrazole, providing a very mild conversion of pyrimidines into pyrazoles. This reaction provided a convenient route to precursors for new efficient and insensitive explosives.