Carbohydrate Research
2012-05-15
Tetraisopropyldisiloxane-1,3-diyl as a versatile protecting group for pentopyranosides.
Richard Johnsson, Richard Johnsson
文献索引：Carbohydr. Res. 353 , 92-5, (2012)
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摘要
The protecting group tetraisopropyldisiloxane-1,3-yl has been investigated for simultaneous protection of two hydroxyls on pentopyranosides. Methyl α-D-xylopyranoside is protected in excellent regioselectivity and high yield to form the 2,3-protected xylopyranoside whereas methyl β-D-xylopyranoside gives the 3,4-protected product also with excellent regioselectivity.Copyright © 2012 Elsevier Ltd. All rights reserved.
相关化合物
| 结构式 | 名称/CAS号 | 分子式 | 全部文献 |
|---|---|---|---|
 |
甲基 β-吡喃木糖苷
CAS:612-05-5 |
C6H12O5 |
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