Reactions of Unsaturated Compounds with Iodine—Amine Complexes. I. Reactions of Benzalacetophenone and Benzalacetone

PL Southwick, DR Christman

文献索引：Southwick; Christman Journal of the American Chemical Society, 1952 , vol. 74, p. 1886,1890

全文：HTML全文

被引用次数: 32

摘要

Complexes of iodine with ammonia, cyclohexylamine, benzylamine, rnorpholine and piperidine have all been found to react reddily with benzalacetophenone. When sufficient additional amounts of ammonia or the amine are present, good yields can usually be obtained of 2-phenyl-3-benzoylethylenimines from ammonia or the primary amines, and of a,@-diaminobenzylacetophenones from the secondary amines. Benzalacetone reacts ...