The Journal of Organic Chemistry

Reactions of 1, 1-disubstituted olefins containing electron-attracting substituents with methylphenyldiazomethanes

W Nagai, Y Hirata

文献索引：Nagai,W.; Hirata,Y. Journal of Organic Chemistry, 1978 , vol. 43, # 4 p. 626 - 630

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被引用次数: 8

摘要

1, 3-Bis (dimethylamino)-5-aminopentane (27). A slurry of 18 g of nitrile 26, 50 mL of THF, 20 g of" 3, and 10 g of Raney cobalt was shaken under 1000 psi of Hz at 135" C/6 h. Distillation gave 7 g of triamine, bp 84-90" C (2 mm); IR primary aliphatic amine;'H NMR6 1.12 (s, NHz), 1.2-1.8 (m, 4 H), 2.11, 2.17 (s, s, NCHB), 2.27-2.79 (m, 5 H). Anal Calcd for CgHz3N3: C, 62.4; H, 13.4; N, 24.2. Found: C, 62.2; H, 13.4; N, 24.2.