Convenient methods for the preparation of di (1??alkynyl) sulfides, sulfoxides and sulfones, and application of the sulfoxides and sulfones in the formation of novel …
W Verboom, M Schoufs, J Meijer…
文献索引：Verboom,W. et al. Recueil des Travaux Chimiques des Pays-Bas, 1978 , vol. 97, p. 244 - 246
Abstract Di (1-alkynyl) sulfides and the corresponding sulfoxides are obtained in high yields from lithium alkynides and sulfur dichloride or thionyl chloride, respectively. The di (1- alkynyl) sulfoxides and also the corresponding sulfones (prepared by oxidation of di (1- alkynyl) sulfides with m-chloroperbenzoic acid) react very rapidly with disodium sulfide, selenide or telluride to form six-membered heterocyclic compounds.
