The Journal of Organic Chemistry

A New Synthesis of Diarylmethylphosphonic Acids and Their Esters from Aromatic Ketones and Trialkyl Phosphites1

AC Poshkus, JE Herweh

文献索引：Poshkus,A.C.; Herweh,J.E. Journal of Organic Chemistry, 1964 , vol. 29, p. 2567 - 2571

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被引用次数: 14

摘要

Although the reaction of quinones2 and of vicinal dike tone^^-^ with trialkyl and triaryl phosphites has been studied extensively, siniple ketones have been neglected. Acetone6 and 4-methyl-4-dichloroinethylcyclohexadien-1-one7 are inert to triethyl phosphite but cyclohexanone reacts with diphenyl K-phenylphosphoramidi te to give an a- phenoxyphosphonaniidateg; benzophenone is claimed, without supporting experimental ...