Journal of fluorine chemistry

Synthesis of cyclenphosphoranes with polyfluorophenyl substituents; an X-ray structure of N-methyl cyclen-p-(heptafluorotolyl) phosphorane

OD Gupta, RL Kirchmeier, JM Shreeve

文献索引：Gupta; Kirchmeier, Robert L.; Shreeve, Jeanine M. Journal of Fluorine Chemistry, 1999 , vol. 97, # 1-2 p. 223 - 228

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被引用次数: 3

摘要

The metathesis reactions between the lithiated derivative of cyclenphosphorane (2) and octafluorotoluene, hexafluorobenzene, pentafluorobenzonitrile, pentafluoronitrobenzene, pentafluoro-n-butylbenzene, pentafluorobenzene and p-(cyanotetrafluorophenoxy- pentafluorobenzene) under reflux conditions gave cyclen-p-(heptafluorotolyl) phosphorane (3), cyclen-p-(pentafluorophenyl) phosphorane (4), cyclen-p-(cyanotetrafluorophenyl) ...