Search for radical rearrangement in organosilicon systems. I.. alpha.-Silyl radicals from silaneophyl systems

JW Wilt, O Kolewe, JF Kraemer

文献索引：Wilt,J.W. et al. Journal of the American Chemical Society, 1969 , vol. 91, p. 2624 - 2631

全文：HTML全文

被引用次数: 36

摘要

Abstract: The triphenylsilylmethyl radical (l), generated by the di-t-butyl peroxide decarbonylation of neat P, P, P-triphenylsilylacetaldehyde (4), did not rearrange under the conditions employed. Only triphenylmethylsilane (10) resulted. Dilution of 4 in chlorobenzene did not alter the result. This same radical, as well as the phenyldimethylsilylmethyl (silaneophyl) and trimethylsilylmethyl (silaneopentyl) radicals 2 ...