Stereospecific Reactions of Nucleophilic Agents with Acetylenes and Vinyl-type Halides. VIII. The Mechanism of the Reaction of Tetrachloroethylene with p- …

WE Truce, R Kassinger

文献索引：Truce; Kassinger Journal of the American Chemical Society, 1958 , vol. 80, p. 6450

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被引用次数: 23

摘要

Although the reaction of tetrachloroethylene with thiolates has been known for some time, 5 its stereochemical and mechanistic course was unknown. It was observed in this Laboratory that tetrachloroethylene undergoes a stereospecific reaction with sodium p-toluenethiolate, the product being cis-l, 2-dichloro-1, 2-di-(p-tolylmercapto)-ethene. Previously we had demonstrated that the reaction of vinylidine chloride with sodium p-toluenethiolate ...