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Intramolecular charge transfer properties of dicyanovinyl-substituted aromatics

AR Katritzky, DW Zhu, KS Schanze

文献索引:Katritzky, Alan R.; Zhu, Dong-Wei; Schanze, Kirk S. Journal of Physical Chemistry, 1991 , vol. 95, # 15 p. 5737 - 5742

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被引用次数: 29

摘要

A series of five dicyanovinyl (DCV)-substituted aromatic compounds (referred to collectively as Ar-DCV, where Ar= 1-phenyl, 1-napthyl, 9-anthracenyl, 9-phenanthrenyl, and 1-pyrenyl) were prepared and their ground-and excited-state properties were examined. Solvent- dependent NMR studies indicate that the ground state of the Ar-DCV compounds is polar. Strong intramolecular charge transfer (ICT) absorption bands were observed for each ...