Organic Letters 2007-10-25

Efficient preparation of N-phenylsulfenyl ketimines from oximes or nitro compounds without racemization of alpha-stereocenters.

Jordi Burés, Carles Isart, Jaume Vilarrasa

文献索引：Org. Lett. 9(22) , 4635-4638, (2007)

摘要

As N-sulfenyl imines (e.g., RR'C=N-SAr) can be readily transformed to their N-sulfinyl imines (RR'C=N-SOAr), N-sulfonyl imines (RR'C=N-SO2Ar), and N-sulfonyl oxaziridines, the very mild procedure developed to convert ketoximes and secondary nitro derivatives to N-arenesulfenyl ketimines constitutes a new and efficient route to all these series of compounds. The configuration of the alpha-stereocenters is retained.

结构式	名称/CAS号	分子式	全部文献
	N-(苯硫基)邻苯二甲酰亚胺 CAS:14204-27-4	C₁₄H₉NO₂S

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Efficient preparation of N-phenylsulfenyl ketimines from oximes or nitro compounds without racemization of alpha-stereocenters.

摘要

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