Journal of the American Chemical Society

The reaction of nitric oxide with isobutylene

JF Brown Jr

文献索引：Brown Journal of the American Chemical Society, 1957 , vol. 79, p. 2480,2487

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被引用次数: 89

摘要

Nitric oxide containing traces of nitrogen dioxide reacts readily with liquid isobutylene to give nitrogen and a mixture of nitrated products. This mixture is believed to contain 6- nitrqisobutylene (22%); nitro-t-butanol (9%); traces of isobutylene pseudonitrosite, nitro-t- butyl nitrate and a-hydroxyiinbutyraldoxime; and major amounts (6B70) of a substance having the partial structure (nitro-t-butyl) 4iY202. The latter is very unstable and ...