A novel catlytic synthesis of vinyl carboamtes from carbon dioxide, diethylamine, and alkynes in the presence of Ru 3 (CO) 12

Y Sasaki, PH Dixneuf

文献索引：Sasaki, Yoshiyuki; Dixneuf, Pierre H. Journal of the Chemical Society, Chemical Communications, 1986 , # 10 p. 790 - 791

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被引用次数: 49

摘要

Vinyl carbamates are useful derivatives as agricultural chemi- cals, pesticides, intermediates for pharmaceutical products or monomers for transparent polymers or varnish. 1 General procedures are known which lead to alkyl carbamates by addition of alcohols to isocyanates or reaction of amines with chloroformates. However, these routes cannot be directly used for access to vinyl carbamates. Vinyl carbamates have previously been made via dehydrohalogenation of a- ...