Isomerisation of allyl ethers to vinyl ethers catalysed by palladium on carbon

HAJ Carless, DJ Haywood

文献索引：Carless, Howard A. J.; Haywood, David J. Journal of the Chemical Society, Chemical Communications, 1980 , # 20 p. 980 - 981

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被引用次数: 18

摘要

Summary Several allyl ethers are cleanly converted into the corresponding prop- 1-enyl ethers on heating in benzene or toluene in the presence of palladium on carbon. ... THE preparation of vinyl ethers has become important,l both in terms of the synthetic use of the aliphatic Claisen rearrangementJ2 and in the use of metallated derivatives of vinyl ethers as 'masked' acyl equivalents 3 In the carbohydrate field, especially, allyl ethers have been used as selective protecting ...