Chemistry Letters

PHOTOCHEMISTRY OF DIBENZO-1, 1, 2, 2, 3, 3-HEXAMETHYL-1, 2, 3-TRISILACYCLOHEPTA-4, 6-DIENE AND THE GERMANIUM ANALOG. GENERATION OF …

H Sakurai, K Sakamoto, M Kira

文献索引：Sakurai, Hideki; Sakamoto, Kenkichi; Kira, Mitsuo Chemistry Letters, 1984 , p. 1379 - 1382

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被引用次数: 31

摘要

Photolysis of the title compound afforded silafluorene and dibenzo-1, 2- disilacyclohexadiene as primary photoproducts. Two reactive intermediates, tetramethyldisilene and dimethylsilylene, were detected by trapping. The dimethylgermylene, derived from the germanium analog, was first observed by electronic spectra.