Alkylation of Carbonyl Compounds in Water: Formation of C C and C O Bonds in the Presence of Surfactants

…, S Cerritelli, M Chiarini, P De Maria…

文献索引：Cerichelli, Giorgio; Cerritelli, Simona; Chiarini, Marco; De Maria, Paolo; Fontana, Antonella Chemistry - A European Journal, 2002 , vol. 8, # 22 p. 5204 - 5210

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被引用次数: 18

摘要

Abstract The formation of C [BOND] C and C [BOND] O bonds by the reaction of enolate intermediates with electrophilic substrates commonly requires strong bases, aprotic solvents and very low temperatures. A way of performing the same reactions with sodium hydroxide at moderate temperatures in aqueous surfactant solutions is presented. Different halides, ketones and surfactants (cationic, zwitterionic and anionic) have been used. The results ...