前往化源商城

Nitroalkanes from Conjugated Nitroalkenes by Reduction with Complex Hydrides1

H Shechter, DE Ley…

文献索引:Shechter et al. Journal of the American Chemical Society, 1956 , vol. 78, p. 4984,4985

全文:HTML全文

被引用次数: 96

摘要

Sodium trimethoxyborohydride, lithium borohydride, sodium borohydride and lithium aluminum hydride are satisfactory reducing agents for converting conjugated nitroalkenes to their corresponding nitroalkanes. The reduction reactions are accompanied by consecutive processes in which the initial reduction products add to the parent nitroolefins to give salts of the corresponding 1, 3-dinitroalkanes and related polynitroalkanes of higher molecular ...