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Synlett

Palladium-Catalyzed Double Cross-Coupling Reaction of vic-Diborylalkenes and-arenes with vic-Bromo (bromomethyl) arenes

M Shimizu, Y Tomioka, I Nagao, T Hiyama

文献索引:Shimizu, Masaki; Tomioka, Yosuke; Nagao, Ikuhiro; Hiyama, Tamejiro Synlett, 2009 , # 19 p. 3147 - 3150

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摘要

Abstract Efficient annulation of vic-diborylalkenes and-arenes with vic-bromo (bromomethyl) arenes has been achieved, using Pd (PPh 3) 4 as a catalyst in the presence of Cs 2 CO 3 and water in THF at 60 C, giving rise to the corresponding indene and fluorene derivatives in good to high yields.