The Journal of Organic Chemistry

Transition-metal catalyzed oxidations. 7. Zirconium-catalyzed oxidation of primary and secondary alcohols with hydroperoxides

K Krohn, I Vinke, H Adam

文献索引：Krohn, Karsten; Vinke, Ingeborg; Adam, Horst Journal of Organic Chemistry, 1996 , vol. 61, # 4 p. 1467 - 1472

全文：HTML全文

被引用次数: 67

摘要

A new procedure for the oxidation (dehydrogenation) of primary and secondary alcohols employing Zr (Ot-Bu) 4 or Zr (On-Pr) 4/tert-butyl hydroperoxide/3 Å molecular sieves is presented. Secondary alcohols if not severely sterically hindered are usually converted quantitatively to the corresponding ketones. Esters or acids can be byproducts in the reaction of primary alcohols. However, the aldehydes are obtained in good yield by ...