Organic Letters 2003-10-02

Total synthesis of 10-norparvulenone and of O-methylasparvenone using a xanthate-mediated free radical addition-cyclization sequence.

Alejandro Cordero Vargas, Béatrice Quiclet-Sire, Samir Z Zard

文献索引：Org. Lett. 5(20) , 3717-9, (2003)

全文：HTML全文

摘要

[reaction: see text] A short synthesis of (+/-)-10-norparvulenone and (+/-)-O-methylasparvenone was developed starting from commercially available m-methoxyphenol, hinging on a xanthate-mediated addition-cyclization sequence for the construction of the alpha-tetralone subunit.