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Synthesis of tricyclic phospholene oxides by cycloaddition of phosphorus halides with heterocyclic analogs of 1??vinyl??3, 4??dihydronaphthalenes

…, MD Gordon, JE Macdiarmid

文献索引:Quin, Louis D.; Gordon, Michael D.; MacDiarmid, Joan E. Journal of Heterocyclic Chemistry, 1982 , vol. 19, p. 1041 - 1044

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被引用次数: 3

摘要

Abstract Replacement of C-4 with a hetero substituent (NR, O, S) in the 1-vinyl-3, 4- dihydronaphthalene system has provided a new type of diene for participation in the McCormack cycloaddition reaction with P (III) halides. The tricyclic phospholene oxides so obtained are the first to bear an additional heteroatom in the ring system. 1, 2-Dihydro-7- methoxy-1-(p-toluenesulfonyl)-4-vinylquinoline is a stable solid that reacts with ...