An Efficient and Recyclable Catalyst for N??Alkylation of Amines and β??Alkylation of Secondary Alcohols with Primary Alcohols: SBA??15 Supported N??Heterocyclic …

D Wang, XQ Guo, CX Wang, YN Wang…

文献索引：Wang, Dong; Guo, Xu-Qing; Wang, Chen-Xi; Wang, Ya-Nong; Zhong, Rui; Zhu, Xiao-Han; Cai, Li-Hua; Gao, Zi-Wei; Hou, Xiu-Feng Advanced Synthesis and Catalysis, 2013 , vol. 355, # 6 p. 1117 - 1125

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被引用次数: 28

摘要

Abstract A mesoporous silica (SBA-15)-supported pyrimidine-substituted N-heterocyclic carbene iridium complex was prepared and used as a catalyst for both environmentally friendly N-alkylation of amines and β-alkylation of secondary alcohols with primary alcohols. The structure of the supported iridium catalyst was characterized by Fourier transform infrared (FT-IR), 13 C and 29 Si solid-state nuclear magnetic resonance (NMR), small- ...