Israel Journal of Chemistry

Synthesis of Compounds Related to Steroids. Reactions of β??Methyltricarballylic Acid Anhydride with Benzene and Naphthalene

M Harnik

文献索引：Harnik,M. Israel Journal of Chemistry, 1965 , vol. 3, p. 1 - 11

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被引用次数: 2

摘要

Abstract β-Methyltricarballylic acid anhydride (I) undergoes an efficient three-step reaction sequence whereby it is transformed into known intermediates useful in the synthesis of aromatic steroids. Experiments are described in the benzene series leading to the preparation of the tetralone derivative (VIIa), and in the naphthalene series giving the tetrahydrophenanthrene acids (XV) and (XIII).