REACTIVITY OF THE ACIDS OF TRIVALENT PHOSPHORUS AND THEIR DERIVATIVES. PART IX. THE> P-0− AND> PS− NUCLEOPHILES IN THE REACTIONS OF …

L Dembkowski, D Witt, J Rachon

文献索引：Dembkowski, Leszek; Witt, Dariusz; Rachon, Janusz Phosphorus, Sulfur and Silicon and Related Elements, 1997 , vol. 127, p. 143 - 157

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被引用次数: 4

摘要

Abstract The reaction of the> PY−(Y= O; S) nucleophiles with the compounds possessing a C-Br bond and electron-withdrawing groups is described. The isolation of the products derived from dialkyl bromophosphates, the results of the 31P NMR studies, as well as the isolation of bromothiophosphate from the reaction mixture of> PS− nucleophile and methyl α- bromocarboxylate, are further evidence for halophilic substitution as the principal process ...