Chemistry Letters

Pt-Catalyzed Oxidative Rearrangement of Cyclic Tertiary Allylic Alcohols to Enones Using Aqueous Hydrogen Peroxide

T Nagamine, Y Kon, K Sato

文献索引：Nagamine, Takashi; Kon, Yoshihiro; Sato, Kazuhiko Chemistry Letters, 2012 , vol. 41, # 7 p. 744 - 746

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被引用次数: 2

摘要

An oxidative rearrangement of cyclic tertiary allylic alcohols to β-disubstituted α, β- unsaturated ketones by Pt black catalyst with aqueous hydrogen peroxide is described. The reaction proceeds under organic solvent-and halide-free conditions and gives only water as a coproduct. The Pt black catalyst is commercially available and can be reused at least four times.