Synthesis of new functional acenaphthylene derivatives. 2. Regioselective electrophilic substitution of silylated acenaphthenes and acenaphthylenes

…, M Laguerre, J Dunogues, R Calas

文献索引：Felix, Guy; Laguerre, Michel; Dunogues, Jacques; Calas, Raymond Journal of Organic Chemistry, 1982 , vol. 47, # 8 p. 1423 - 1427

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被引用次数: 10

摘要

Results Oxidation of 6 or 7 by Harvey's methods gave a complex mixture of products, especially in the case of 7 in which mono-or polydesilylation accompanied the formation of acenaphthylene, acenaphthene, dihydro-or tetrahydroacenaphthene skeletons. In contrast, when oxidation was effected with 2, 3-dichloro-5, 6-dicyano-p-benzoquinone