Inorganic Chemistry 2008-01-07

Xenon difluoride induced aryl iodide reductive elimination: a simple access to difluoropalladium(II) complexes.

Ariela W Kaspi, Anette Yahav-Levi, Israel Goldberg, Arkadi Vigalok

文献索引：Inorg. Chem. 47(1) , 5-7, (2008)

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摘要

Palladium(II) aryliodo complexes bearing chelating diphosphine ligands react with XeF2, giving iodoarene and rare palladium(II) difluoro complexes. The reaction is general with regard to the aryl group, with even C6F5-I undergoing facile reductive elimination from a Pd center.