Vinyl Derivatives of the Metals. VI. Preparation, Properties and Some Reactions of Trivinyl Compounds of Group V Elements1, 2

…, D Seyferth, FGA Stone, EG Rochow

文献索引：Maier, L.; Seyfert, D.; Stone, F. G. A.; Rochow, E. G. Journal of the American Chemical Society, 1957 , vol. 79, p. 5884 - 5889

全文：HTML全文

被引用次数: 58

摘要

Trivinyl compounds of Group V elements have been prepared by the reaction between vinyl Grignard reagent and the appropriate trihalide. Some physical properties of these trivinyl derivatives are reported, and several new addition compqunds of the type [(CH,: CH) aRMv] X are described. The ability to form" onium" type adducts decreases in passing from trivinylphosphine to triv~ nylblsmuth. Trivinylarsine and-stibine form complex compounds [ ...